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Methods for studying acidic crater lakes.

Methods for studying acidic crater lakes include chemical and isotopic analysis of water and gas samples, in-situ measurements of water properties like pH and temperature, hydroacoustic surveys to study gas bubble flux, and remote sensing techniques like thermal imaging. Chemical modeling is also used to understand the lake's geochemical processes and predict potential hazards.

An Autonomous Boat to Investigate Acidic Crater Lakes



A novel aquatic drone ventured into highly acidic waters to test the feasibility of remotely exploring and surveying hazardous volcanic lakes.




Drone monitoring of volcanic lakes in Costa Rica: a new approach



For the first time ever, samples were collected from volcanic lake waters in Costa Rica using an unmanned aerial vehicle (drone), which represents a major achievement in human–machine interaction and innovation in the technology sector. A Matrice 600 Pro drone was used for remote sampling in the hyperacid crater lake of the Poás volcano, the mildly acidic Lake Botos, and the nearly neutral Lake Hule. A bailer bottle of 250 mL and a HOBO temperature probe, mounted on the drone, were deployed using a specially designed delivery retrieval system. A comparison was carried out relating to the geochemistry of lake water collected by drone as opposed to the hand-collected samples. The SO4−2/Cl ratios of the two samples at Poás hyperacid crater lake were similar, (1.1 ± 0.2) on average, an indication of a lake with homogenous water composition. The Lake Hule showed a similar composition to that registered 20 years ago. The waters from Lake Botos showed some differences, which may be explained by the influence of springs at the bottom of the lake, but the Wilcoxon's signed-rank test showed a good exhibit of a satisfactory level of similarity. Autonomous navigation proves to be very useful for faster, more efficient, reliable, and less hazardous sampling of volcanic lakes.




Field Report: Autonomous Lake Bed Depth Mapping by a Portable Semi-submersible USV at Mt. Zao Okama Crater Lake


Abstract— This work presents a design and a field test result of a small USV system that has portability and wind tolerance for a lake bed depth mapping of volcanic crater lakes. The depth map of the crater lakes indicates an amount of water, crater wall caving, and volcanic upthrust, which is used for volcanic disaster prevention. However, todayfs depth surveillance is achieved by using a manned canoe on a lake in high-altitude, strong-winded, and restricted areas. This research is aiming to realize the autonomous Unmanned Surface Vehicle (USV) for volcanic crater lake surveillance in reducing risks to surveyors. In this research, the authors have developed the lightweight semisubmersible USV system with a high draft that has portability and wind tolerance. The result of a field test at Mt. Zao Okama Crater Lake is shown. A depth map of the north half of the Okama Crater Lake was autonomously measured by using the USV system.




Hydrochemical and Hydroacoustic Investigation of the Yugama Acid Crater Lake, Kusatsu-Shirane, Japan


The gases dissolved in the waters of volcanic lakes can present a serious hazard if the physical-chemical conditions change due to variations in the supply of magmatic gases. The monitoring of gases such as CO2 and He help us understand the degassing process and their connection with magmatic/hydrothermal system. One of the most acidic volcanic lakes on the planet is the Yugama, on Kusatsu Shirane volcano (Japan). We report the results of an interdisciplinary study carried out in August 2013 at Yugama consisting of the first estimation of rate of diffuse CO2 emission, the chemical and isotopic analysis of water and dissolved gases in samples from vertical lake profiles, and an echo-sounding survey. The lake water has an average temperature of 24-25°C, pH 1.01, concentrations of SO42- between 1,227 and 1,654 mgL−1 and Cl between 1,506 and 2,562 mgL−1, with gas bubbling at several locations and floating sulfur globules with sulfide inclusions. A total of 66 CO2 efflux measurements were taken at the lake surface by means of the floating accumulation chamber method to estimate the diffuse CO2 output from the studied area. CO2 efflux values ranged from 82 up to 25,800 g m−2 d−1. Estimation of the diffuse CO2 emission at Yaguma Crater Lake was 30 ± 12 t d−1. Normalized CO2 emission rate (assuming an area of 0.066 km2) was 454 t km−2 d−1, a value within the range of acid volcanic lakes. Vertical profiles of major ions and dissolved gases showed variations with increases in ion content and dissolved CO2 and He with depth. Acoustic imaging shows the presence of intense bubbling and provides important information on the bathymetry of the lake. The 50–200 kHz echograms exhibit frequent vertical plumes of rising gas bubbles. Within the crater-lake, three circular submarine vents have been identified showing flares due to a significant activity of sublacustrine emissions. This work shows the first data of diffuse CO2 degassing, dissolved gases in water and echosounding (ES) from Yugama Crater Lake. Periodic hydrogeochemical and hydroacoustic surveys at Yugama Crater Lakemay thus help to document changes in the state of activity of this high-risk volcanic area.




Geochemical monitoring of volcanic lakes. A generalized box model for active crater lakes ABSTRACT In the past, variations in the chemical contents (SO4 2−, Cl−, cations) of crater lake water have not systematically demonstrated any relationships with eruptive activity. Intensive parameters (i.e., concentrations, temperature, pH, salinity) should be converted into extensive parameters (i.e., fluxes, changes with time of mass and solutes), taking into account all the internal and external chemical–physical factors that affect the crater lake system. This study presents a generalized box model approach that can be useful for geochemical monitoring of active crater lakes, as highly dynamic natural systems. The mass budget of a lake is based on observations of physical variations over a certain period of time: lake volume (level, surface area), lake water temperature, meteorological precipitation, air humidity, wind velocity, input of spring water, and overflow of the lake. This first approach leads to quantification of the input and output fluxes that contribute to the actual crater lake volume. Estimating the input flux of the "volcanic" fluid (Qf - kg/s) –– an unmeasurable subsurface parameter –– and tracing its variations with time is the major focus during crater lake monitoring. Through expanding the mass budget into an isotope and chemical budget of the lake, the box model helps to qualitatively characterize the fluids involved. The (calculated) Cl− content and dD ratio of the rising "volcanic" fluid defines its origin. With reference to continuous monitoring of crater lakes, the present study provides tips that allow better calculation of Qf in the future. At present, this study offers the most comprehensive and up-to-date literature review on active crater lakes.